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Расчёт коэффициентов активности для НС1 3 страница
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| Продолжение таблицы
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| MnO
|
| кр
|
| –385100
| –363340
| 61, 50
| 44, 10
| 46, 48
| 8, 12
| –3, 68
| 298–1800
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| |
| MnO2
|
| кр
|
| –521490
| –466680
| 53, 14
| 54, 02
| 69, 45
| 10, 21
| –16, 23
| 298–523
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| |
| NH3
| аммиак
| г
|
| –45940
| –16480
| 192, 66
| 35, 16
| 29, 80
| 25, 48
| –1, 67
| 298–1800
| 405, 6
| 111, 5
| 0, 242
| |
| NO
| оксид азота
| г
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|
| 210, 64
| 29, 86
| 29, 58
| 3, 85
| –0, 59
| 298–2500
| 180, 3
| 64, 6
| 0, 251
| |
| NOCl
| нитрозил-хлорид
| г
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|
| 263, 50
| 39, 37
| 44, 89
| 7, 70
| –6, 95
| 298–2000
| 438, 2
| 92, 4
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| |
| NO2
| диоксид азота
| г
|
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| 240, 06
| 36, 66
| 41, 16
| 11, 33
| –7, 02
| 298–1500
| 431, 0
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| |
| N2O
| закись азота
| г
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| 219, 83
| 38, 62
| 45, 69
| 8, 62
| –8, 53
| 298–2000
| 309, 7
| 71, 7
| 0, 271
| |
| N2O4
|
| г
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|
| 304, 35
| 79, 16
| 83, 89
| 39, 75
| –14, 90
| 298–1000
| 431, 2
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| |
| N2O5
|
| г
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|
| 355, 69
| 95, 28
| 127, 45
| 16, 54
| –32, 85
| 298–2000
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| NaCl
|
| кр
|
| –411120
| –384130
| 72, 13
| 50, 81
| 45, 94
| 16, 32
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| 298–1070
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| | NaOH
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| кр
|
| –426350
| –380290
| 64, 43
| 59, 66
| 7, 34
| 125, 00
| 13, 58
| 298–566
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| |
| Na2O
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| кр
|
| –417980
| –379260
| 75, 06
| 68.89
| 77, 11
| 19, 33
| –12, 59
| 298–1000
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| NiCl2
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| кр
|
| –304180
| –258030
| 98, 07
| 71, 67
| 73, 27
| 13, 23
| –4, 98
| 298–1300
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| NiO(a)
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| кр
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| –239740
| –211600
| 37, 99
| 44, 31
| –20, 88
| 157, 23
| 16, 28.
| 298–525
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| PCl3
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| г
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| –287020
| –267980
| 311, 71
| 71, 84
| 80, 11
| 3, 10
| 7, 99
| 298–1000
| 324, 5
| 64, 5
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| PtCl2
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| кр
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| –106690
| –93370
| 219, 79
| 75, 52
| 67, 78
| 25, 98
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| 298–854
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| RaCl2
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| кр
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| –887600
| –842900
| 144, 4
| 80, 25
| 77, 04
| 10, 9
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| 298–1000
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| SO2
| диоксид серы
| г
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| –296900
| –300210
| 248, 07
| 39, 87
| 46, 19
| 7, 87
| –7, 70
| 298–2000
| 430, 7
| 77, 8
| 0, 268
| | SO2Cl2
| хлористый сульфурил
| ж
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| –394130
| –321490
| 216, 31
| 133, 89
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| 219–342
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| | SO2Cl2
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| г
|
| –363170
| –318850
| 311, 29
| 77, 40
| 87, 91
| 16, 15
| 14, 23
| 298–1000
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| Продолжение таблицы
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| | SO3
| Трех-окись серы
| г
| –
| –395850
| –371170
| 256, 69
| 50, 09
| 64, 98
| 11, 75
| –16, 37
| 298–1300
| 461, 4
| 88, 8
| 0, 262
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| SbCl2
|
| кр
| –
| –381160
| –322450
| 183, 26
| 110, 46
| 43, 10
| 213, 80
| –
| 273–346
| –
| –
| –
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| Sb2O3
|
| кр
| –
| –715460
| –636060
| 132, 63
| 111, 76
| 92, 05
| 66, 11
| –
| 298–930
| –
| –
| –
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| SiCl4
|
| ж
| –
| –687850
| –620750
| 239, 74
| 145, 27
| 145, 27
| –
| –
| 298–330
| –
| –
| –
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| |
| SiCl4
|
| г
| –
| –657520
| –617620
| 330, 95
| 90, 37
| 101, 46
| 6, 86
| –11, 51
| 298–1000
| 506, 2
| 37, 1
| –
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| |
| SiO2
| Cтекло
| тв
| –
| –903490
| –850710
| 46, 86
| 44, 35
| 56, 02
| 15, 41
| –14, 44
| 298–2000
| –
| –
| –
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| |
| SnCl4
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| ж
| –
| –528866
| –457740
| 258, 99
| 165, 27
| 165, 27
| –
| –
| 298–388
| –
| –
| –
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| |
| SnCl4
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| г
| –
| –489110
| –449550
| 364, 84
| 98, 32
| 106, 98
| 0, 84
| –7, 87
| 298–1000
| –
| –
| –
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| |
| TiCl4
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| ж
| –
| –804160
|
| 252, 40
| 145, 20
| 142, 79
| 8, 71
| –0, 14
| 298–410
| –
| –
| –
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| |
| TiCl4
|
| г
| –
| –763160
|
| 354, 80
| 95, 45
| 107, 18
| 0, 47
| –10, 55
| 298–2000
| –
| –
| –
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| | ZnCl2
|
| кр
| –
| –415050
| –369390
| 111, 46
| 67, 53
| 60, 67
| 23, 01
| –
| 298–550
| –
| –
| –
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| |
| ZnCl2
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| г
| –
| –265680
| –269240
| 276, 54
| 54, 90
| 60, 25
| 0, 84
| –
| 1005–2000
| –
| –
| –
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| ZrCl4
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| кр
| –
| –979770
| –889270
| 181, 42
| 119, 77
| 124, 97
| 14, 14
| –8, 37
| 298–607
| –
| –
| –
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| |
| ZrCl4
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| г
| –
| –869310
|
| 368, 19
| 98, 32
| 107, 46
| 0, 29
| –8, 20
| 607–2000
| –
| –
| –
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| | ZrO2
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| кр
| –
| –1097460
| –1039720
| 50, 36
| 56, 05
| 69, 62
| 7, 53
| –14, 06
| 298–1480
| –
| –
| –
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| Органические соединения
Углеводороды
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| | Фор-мула
| Название
| Ф.с.
| , Дж× моль-1
| , Дж× моль-1
| , Дж× моль-1
| , Дж× моль-1× К-1
| Теплоемкость, Дж× моль-1× К-1
| Темпер. интервал
| Т кр, К
| Р кр, атм
| Z кр
| |
| а
| b × 103
| c × 106
| |
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| CH4
| метан
| г
| –890355
| –74847, 5
| –50793
| 186, 18
| 35, 714
| 17, 451
| 60, 458
| 1, 117
| 298–1500
| 191, 6
| 46, 0
| 0, 29
| |
| C2H2
| ацетилен
| г
| –1299634
|
|
| 198, 735
| 43, 927
| 21, 242
| 85, 767
| –58, 34
| 298–1500
| 308, 3
| 61, 6
| 0, 274
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| C2H4
| этилен
| г
| –126398
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| 219, 450
| 43, 555
| 4, 196
| 154, 59
| –81, 09
| 298–1500
| 282, 4
| 50, 5
| 0, 270
| |
| C2H4
| этан
| г
| –1559878
| –84667
| –32886
| 229, 492
| 52, 655
| 4, 493
| 182, 26
| –74, 85
| 298–1500
| 305, 5
| 48, 2
| 0, 285
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| C3H4
| пропин
| г
| –1937652
|
|
| 248, 111
| 60, 668
| 18, 451
| 157, 36
| 60, 16
| –
| 401, 0
| 52, 8
| 0, 270
| |
| C3H4
| пропа-диен (аллен)
| г
| –1944346
|
|
| 243, 927
| 58, 994
| 15, 146
| 151, 33
| –50, 87
| 273–1200
| 303, 2
| 43, 5
| 0, 281
| |
| C3H6
| пропен
| г
| –2058486
|
|
| 266, 939
| 63, 889
| 3, 305
| 235, 86
| –117, 6
| 298–1500
| 305, 0
| 45, 6
| 0, 274
| | C3H6
| цикло-пропан
| г
| –
|
|
| 237, 693
| 55, 228
| –
| –
| –
| –
| 397, 8
| 54, 2
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| C3H8
| пропан
| г
| –2220030
| –103846
| –23488
| 269, 909
| 73, 512
| –4, 799
| 307, 31
| –160, 2
| 298–1500
| 370, 0
| 42, 0
| 0, 277
| |
| C4H6
| 1, 3-бу-тадиен (диви-нил)
| г
| –2541738
|
|
| 278, 738
| 79, 537
| –2, 958
| 340, 08
| –223, 7
| 298–1500
| 425, 2
| 42, 7
| 0, 271
| |
| C4H6
| 1-бутин
| г
| –2596757
|
|
| 290, 829
| 81, 420
| 13, 459
| 270, 03
| 149, 19
| –
| 463, 7
| –
| –
| |
| C4H6
| 2-бутин
| г
| –255077
|
|
| 283, 298
| 78, 283
| 15, 083
| 239, 23
| 111, 73
| –
| 488, 7
| –
| –
| |
| C4H6
| 1, 2-бутадиен
| г
| –2593787
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| 293, 005
| 81, 629
| –
| –
| –
| –
| –
| –
| –
| | C4H8
| бутен-1
| г
| –2717298
| –125
|
| 307, 440
| 85, 646
| 21, 47
| 258, 40
| –80, 84
| 298–1500
| 419, 6
| 30, 7
| 0, 271
| | C4H8
| цис-2-бутен
| г
| –2710437
| –5690
|
| 300, 829
| 78, 910
| 8, 564
| 269, 07
| 82, 985
| 298–1500
| 434, 6
| 41, 0
| 0, 268
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| Продолжение таблицы
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| | | C4H8
| транс-2-бутен
| г
| –2706253
| –11171
|
| 296, 478
| 87, 445
| 8, 380
| 307, 54
| –148, 25
| 298–1500
| 428, 6
| 41, 5
| 0, 263
| | |
| C4H8
| 2-метил-пропен (изобутилен)
| г
| –2700479
|
|
| 293, 591
| 89, 119
| 6, 706
| 321, 63
| –166, 07
| 298–1500
| 417, 9
| 39, 5
| 0, 270
| |
| C4H10
| бутан
| г
| –2877127
| –126147
| –17154
| 310, 118
| 97, 445
| 0, 468
| 385, 37
| –198, 88
| 298–1500
| 425, 2
| 37, 5
| 0, 274
| |
| C4H10
| бутан
| ж
| –
| –147635
| –
| –
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C4H10
| изобутан
| г
| –2868759
| –134515
| –20920
| 294, 637
| 96, 817
| –6, 840
| 409, 64
| –220, 54
| 298–1500
| 407, 1
| 36, 0
| 0, 283
| |
| C4H10
| изобутан
| ж
| –
| –158448
| –
| –
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C5H8
| 1-пентин
| г
| –3255277
|
|
| 330, 95
| 106, 69
| 18, 593
| 348, 45
| 188, 19
| –
| –
| –
| –
| |
| C5H8
| 2-пентин
| г
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|
| 331, 79
| 98, 32
| 11, 058
| 341, 28
| 169, 39
| –
| –
| –
| –
| |
| C5H8
| 2-метил-1, 3-бутадиен (изопрен)
| г
| –3186576
|
|
| 315, 64
| 104, 6
| –
| –
| –
| –
| –
| –
| –
| | C5H8
| изопрен
| ж
| –
|
|
| 229, 28
| 153, 13
| –
| –
| –
| –
| –
| –
| –
| |
| C5H8
| циклопе-нтен
| г
| –
|
|
| 247, 81
| 75, 10
| –
| –
| –
| –
| 506, 2
| 47, 2
| 0, 272
| |
| C5H8
| –“–
| ж
| –
|
|
| 201, 25
| 122, 34
| –
| –
| –
| –
| –
| –
| –
| |
| C5H10
| 1-пентен
| г
| –3633804
| –20920
|
| 345, 80
| 109, 97
| 7, 480
| 424, 48
| –231, 90
| –
| 464, 8
| 40, 0
| 0, 266
| |
| C5H10
| –“–
| ж
| –
| –
| –
| 262, 54
| 155, 31
| –
| –
| –
| –
| –
| –
| –
| |
| C5H10
| цис-2-пентен
| г
| –3369542
| –28074
|
| 346, 26
| 101, 75
| –14, 02
| 458, 66
| –252, 48
| –
| 475, 6
| 40, 4
| 0, 266
| |
| C5H10
| –“–
| ж
| –
| –61923
|
| 258, 61
| 151, 71
| –
| –
| –
| –
| –
| –
| –
| |
| C5H10
| 2-метил-1-бутен
| г
| –3360463
| –36317
|
| 341, 95
| 111, 67
| 2, 071
| 435, 07
| –240, 17
| –
| –
| –
| 0, 274
| | | 3-метил-1-бутен
| г
| –3367827
| –2895
|
| 333, 46
| 118, 61
| 13, 681
| 417, 29
| –230, 75
| –
| 464, 8
| 33, 9
| –
|
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| Продолжение таблицы
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| C5H10
| –“–
| ж
| –
|
|
| 253, 29
| 156, 06
| –
| –
| –
| –
| –
| –
| –
| |
| C5H10
С6Н12
| 2-метил-2-бутен
3, 3-диметилбутен-1
| Г
г
| –
| –42551
-43137
|
| 338, 56
343, 75
| 105, 01
126, 48
| 0, 543
| –414, 70
| –209, 69
| –
| 470, 2
| 34, 0
| 0, 266
| |
| C5H10
| –“–
| ж
| –
| –
| –
| 251, 04
| 152, 79
| –
| –
| –
| –
| –
| –
| –
| |
| C5H10
| циклопентан
| г
| –3319543
| –77236
|
| 292, 88
| 82, 92
| –54, 39
| 545, 8
| –307, 72
| 298–1500
| 511, 8
| 44, 6
| 0, 276
| |
| C5H10
| –“–
| ж
| –
| –105855
|
| 204, 26
| 126, 73
| 126, 73
| –
| –
|
| –
| –
| –
| |
| C5H12
| н-пентан
| г
| –3535898
| –146440
| –8368
| 348, 94
| 120, 20
| 1, 44
| 476, 47
| –250, 40
| 298–1500
| 469, 8
| 33, 3
| 0, 269
| |
| C5H12
| –“–
| ж
| –
| –173050
| –9414
| 263, 25
| 172, 79
| –
| –
| –
| –
| –
| –
| –
| |
| C5H12
| 2-метил-бутан (изопентан)
| г
| –3528116
| –154473
| –14644
| 343, 59
| 118, 78
| 9, 28
| 517, 72
| –292, 90
| 298–1500
|
| 33, 7
| 0, 268
| |
| C5H12
| –“–
| ж
| –
| –179284
| –14644
| 261, 58
| 164, 84
| 127, 19
| –
| –
|
| –
| –
| –
| | C5H12
| 2, 2-диметил-пропан
| г
| –3516610
| –165979
| –15229
| 306, 39
| 121, 62
| –15, 10
| 548, 58
| –322, 92
| 298–1500
| 433, 8
| 31, 6
| 0, 269
| |
| C5H12
| (неопентан)
| ж
| –
| –188196
| –14100
| 228, 02
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C6H6
| бензол
| г
| –3301510
|
|
| 269, 19
| 81, 67
| –33, 89
| 471, 87
| –298, 34
| 298–1500
| 562, 7
| 48, 6
| 0, 274
| |
| C6H6
| –“–
| ж
| –
|
|
| 172, 79
| 135, 77
| 59, 49
| 255, 01
| –
| 281–353
| –
| –
| –
| |
| C6H10
| циклогексен
| г
| –
| –40166
|
| 310, 45
| 105, 01
| –
| –
| –
| –
| 559, 2
| 41, 8
| –
| |
| C6H10
| –“–
| ж
| –
|
|
| 216, 18
| 146, 02
| –
| –
| –
| –
| –
| –
| –
| |
| C6H12
| 1-гексен
| г
| –4034463
| –41421
|
| 384, 63
| 132, 33
| 8, 631
| 514, 64
| –282, 00
| –
|
| 31, 1
| 0, 260
| |
| C6H12
| –“–
| ж
| –
| –72295
|
| 295, 18
| 183, 30
| –
| –
| –
| –
| –
| –
| –
| |
| C6H12
| метилцикло-пентан
| г
| –3969444
| –106692
|
| 339, 90
| 109, 78
| –50, 13
| 662, 32
| –364, 49
| –
| 532, 8
| 37, 4
| 0, 273
| | C6H12
| –“–
| ж
| –
| –138364
|
| 247, 94
| 157, 31
| –
| –
| –
| –
| –
| –
| –
| | |
|
|
|
|
|
|
|
|
|
|
|
| Продолжение таблицы
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