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Расчёт коэффициентов активности для НС1 2 страница
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| | S
| сера (монокл.)
| кр
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| 32, 55
| 23, 64
| 23, 64
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|
| 368–392
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| |
| S
| сера (ромб.)
| кр
|
|
|
| 31, 92
| 22, 68
| 22, 68
|
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| 273–368
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| S2
| сера
| г
|
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| 167, 75
| 23, 67
| 23, 67
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| S2
|
| г
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|
| 228, 03
| 32, 51
| 36, 11
| 1, 09
| –3, 51
| 200–298
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| S8
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| г
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| 429, 94
| 155, 43
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| Sb
| сурьма
| кр
|
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| 45, 69
| 25, 23
| 23, 10
| 7, 28
|
| 273–900
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| Se
| селен
| кр
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| 42, 44
| 25, 36
| 18, 95
| 23, 01
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| 273–490
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| Si
| кремний
| кр
|
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|
| 18, 83
| 19, 99
| 22, 82
| 3, 86
| –3, 54
| 298–1685
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| Sn
| олово (бел.)
| кр
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|
| 51, 55
| 26, 99
| 21, 59
| 18, 10
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| 298–505
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| Sn
|
| ж
|
| Dm H =7030
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| 21, 54
| 6, 15
| 12, 88
| 505–800
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|
| Sr
| строн-ций
| кр
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|
| 55, 69
| 26, 36
| 22, 22
| 13, 89
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| 298–830
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| Te
| теллур
| кр
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|
| 49, 50
| 25, 71
| 19, 12
| 22, 09
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| 298–720
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| Th(a)
| торий
| кр
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| 53, 39
| 27, 32
| 23, 56
| 12, 72
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| 298–1600
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| Ti(a)
| титан
| кр
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| 30, 63
| 25, 02
| 21, 10
| 10, 54
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| 298–1155
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| Tl(a)
| таллий
| кр
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| 64, 18
| 26, 32
| 22, 01
| 14, 48
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| 273–500
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| U(a)
| уран
| кр
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| 50, 29
| 27, 66
| 16, 19
| 30, 63
| 2, 05
| 298–940
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| W
| воль-фрам
| кр
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| 32, 64
| 24, 27
| 22, 91
| 4, 69
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| 298–2500
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| Zn
| цинк
| кр
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| 41, 63
| 25, 44
| 22, 38
| 10, 04
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| 273–690
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| Zr(a)
| цир-коний
| кр
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| 38, 99
| 25, 44
| 21, 97
| 11, 63
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| 298–1135
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| Продолжение таблицы
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| Неорганические соединения
| |
| AgBr
|
| кр
|
| –100420
| –97020
| 107, 11
| 52, 30
| 33, 18
| 64, 43
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| 298–700
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| |
| AgCl
|
| кр
|
|
| –109540
| 96, 23
| 50, 79
| 62, 26
| 4, 18
| –11, 30
| 298–725
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| |
| AgI
|
| кр
|
| –61920
| –66350
| 115, 48
| 54, 43
| 24, 35
| 100, 83
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| 298–420
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| |
| AgNO3
|
| кр
|
| –124520
| –33600
| 140, 92
| 93, 05
| 36, 65
| 189, 12
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| 298–433
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| |
| Ag2O
|
| кр
|
| –30540
| –10900
| 121, 75
| 45, 86
| 55, 48
| 29, 46
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| 298–500
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| |
| Ag2S(a)
|
| кр
|
| –31800
| –39700
| 143, 51
| 76, 53
| 64, 60
| 39, 96
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| 298–449
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| |
| Ag2SO4
|
| кр
|
| –715880
| –618360
| 200, 00
| 131, 38
| 96, 65
| 116, 73
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| 298–597
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| |
| AgBr
|
| кр
|
| –513380
| –496600
| 180, 25
| 100, 50
| 49, 95
| 169, 58
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| 298–370
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| | AgCl
|
| кр
|
| –704170
| –628580
| 109, 29
| 91, 00
| 77, 12
| 47, 83
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| 273–453
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| | AgF
|
| кр
|
| –1510420
| –1431150
| 66, 48
| 75, 10
| 72, 26
| 45, 86
| –9, 62
| 298–727
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| | Al2O3
| корунд
| кр
|
| –1675690
| –1582270
| 50, 92
| 79, 04
| 114, 55
| 12, 89
| –34, 31
| 298–1800
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| |
| Al2(SO4)3
|
| кр
|
| –3441800
| –3100870
| 239, 20
| 259, 41
| 366, 31
| 62, 59
| –112, 47
| 298–1100
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| |
| AsCl3
|
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|
| –305010
| –259160
| 216, 31
| 133, 47
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| AsCl3
|
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| –270340
| –258040
| 328, 82
| 75, 48
| 82, 09
| 1, 00
| –5, 94
| 298–2000
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| |
| As2O3
|
| кр
|
| –653370
| –577030
| 122, 72
| 112, 21
| 59, 83
| 175, 73
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| 298–582
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| |
| As2O3
| клау-денит
| кр
|
| –656890
| –576160
| 108, 32
| 95, 65
| 35, 02
| 203, 39
|
| 298–548
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| |
| As2O5
| арсе-нолит
| кр
|
| –921320
| –478690
| 105, 44
| 116, 52
| 116, 52
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| | BCl3
|
| г
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| –402960
| –387980
| 290, 08
| 62, 63
| 70, 54
| 11, 97
| –10, 21
| 298–1000
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| | BF3
|
| г
|
| –1136580
| –1119930
| 254, 01
| 50, 46
| 52, 05
| 28, 03
| –8, 87
| 298–1000
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| Продолжение таблицы
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| B2O3
|
| кр
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| –1270430
| –1191290
| 53, 84
| 62, 76
| 36, 53
| 106, 32
| –5, 48
| 298–723
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|
|
| BaCO3
|
| кр
|
| –1210850
| –1132770
| 112, 13
| 85, 35
| 86, 90
| 48, 95
| –11, 97
| 298–1040
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|
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| BaCl2
|
| кр
|
| –859390
| –811710
| 123, 64
| 75, 31
| 71, 13
| 13, 97
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| 298–1195
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| Ba(NO3)2
|
| кр
|
| –992070
| –797230
| 213, 80
| 151, 63
| 125, 73
| 149, 37
| –16, 74
| 298–868
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| BaO
|
| кр
|
| –553540
| –525840
| 70, 29
| 46, 99
| 53, 30
| 4, 35
| –8, 28
| 298–1270
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| Ba(OH)2
|
| кр
|
| –945490
| –855420
| 100, 83
| 97, 91
| 70, 71
| 91, 43
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| 298–683
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| BaSO4
|
| кр
|
| –1458880
| –1348430
| 132, 21
| 102, 09
| 141, 42
| 0, 0
| –35, 27
| 298–1300
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| BeO
|
| кр
|
| –598730
| –569540
| 14, 34
| 25, 56
| 35, 35
| 16, 74
| –13, 26
| 298–1175
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| BeSO4
|
| кр
|
| –1200810
| –1089450
| 77, 97
| 85, 69
| 71, 78
| 99, 69
| –13, 78
| 298–863
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| Bi2O3
|
| кр
|
| –570700
| –490230
| 151, 46
| 113, 8
| 103, 51
| 33, 47
|
| 298–978
|
|
|
| CO
| оксид
| г
| –282922
| –110530
| –137150
| 197, 55
| 29, 14
| 28, 41
| 4, 10
| –0, 46
| 298–2500
| 132, 9
| 34, 5
| 0, 294
| CO2
| диоксид
| г
|
| –393513
| –394370
| 213, 66
| 37, 11
| 44, 14
| 9, 04
| –8, 54
| 298–2500
| 304, 2
| 72, 9
| 0, 274
|
| COCl2
| фосген
| г
|
| –223007
| –205310
| 283, 64
| 57, 76
| 67, 15
| 12, 03
| –9, 04
| 298–1000
| 455, 2
|
| 0, 285
|
| COS
| серо-окись
| г
| –553124
| –137235
| –168940
| 231, 53
| 41, 55
| 48, 12
| 8, 45
| –8, 20
| 298–1800
| 378, 2
|
|
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| CS2
| серо-углерод
| г
|
|
|
| 151, 04
| 75, 65
| 75, 65
|
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| CS2
|
| кр
|
|
|
| 237, 77
| 45, 48
| 52, 09
| 6, 69
| –7, 53
| 298–1800
| 552, 2
|
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|
| CaCO3
| кальцит
| кр
|
| –1206810
| –1128350
| 91, 71
| 83, 47
| 104, 52
| 21, 92
| –25, 94
| 298–1200
|
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|
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| CaCl2
|
| кр
|
| –795920
| –749340
| 108, 37
| 72, 59
| 71, 88
| 12, 72
| –2, 51
| 298–1055
|
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|
|
| CaF2(a)
|
| кр
|
| –1220890
| –1168460
| 68, 45
| 67, 03
| 59, 83
| 30, 46
| 1, 97
| 298–1000
|
|
|
| CaO
|
| кр
|
| –635090
| –603460
| 38, 07
| 42, 05
| 49, 62
| 4, 52
| –6, 95
| 298–1800
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| Продолжение таблицы
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| |
| Ca(OH)2
|
| кр
|
| –985120
| –897520
| 83, 39
| 87, 49
| 105, 19
| 12, 01
| –19, 00
| 298–600
|
|
|
| |
| CaSO4
| ангидрит
| кр
|
| –1436280
| –1323900
| 106, 69
| 99, 66
| 70, 21
| 98, 74
|
| 298–1400
|
|
|
| |
| CdCl2
|
| кр
|
| –396790
| –343240
| 115, 27
| 73, 22
| 61, 25
| 40, 17
|
| 298–841
|
|
|
| |
| CdO
|
| кр
|
| –258990
| –229330
| 54, 81
| 43, 64
| 48, 24
| 6, 38
| –4, 50
| 298–1500
|
|
|
| |
| Cl2O
|
| г
|
|
|
| 266, 23
| 45, 44
| 53, 18
| 3, 35
| –7, 78
| 298–2000
|
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|
| |
| CoCl2
|
| кр
|
| –312540
| –269690
| 109, 29
| 78, 49
| 60, 29
| 61, 09
|
| 298–1000
|
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| |
| CrCl3
|
| кр
|
| –556470
| –486370
| 123, 01
| 91, 80
| 79, 50
| 41, 21
|
| 298–1217
|
|
|
| |
| CrO3
|
| кр
|
| –590360
| –513440
| 73, 22
| 69, 33
| 82, 55
| 21, 67
| –17, 49
| 298–470
|
|
|
| |
| CsCl
|
| кр
|
| –442830
| –414610
| 101, 18
| 52, 63
| 49, 79
| 9, 54
|
| 298–918
|
|
|
| |
| CuO
|
| кр
|
| –162000
| –134260
| 42, 63
| 42, 30
| 43, 83
| 16, 77
| –5, 88
| 298–1359
|
|
|
| | CuSO4
|
| кр
|
| –770900
| –661790
| 109, 20
| 98, 87
| 78, 53
| 71, 96
|
| 298–900
|
|
|
| | D2O
| тяжелая вода
| ж
|
| –294600
| –243470
| 75, 90
| 84, 31
| 84, 31
|
|
|
|
|
|
| |
| D2O
|
| г
|
| –294200
| –234550
| 198, 23
| 34, 27
| 34, 27
|
|
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| |
| FeCO3
|
| кр
|
| –738150
| –665090
| 95, 40
| 83, 26
| 48, 66
| 112, 13
|
| 298–855
|
|
|
| |
| FeO
|
| кр
|
| –264850
| –244300
| 60, 75
| 49, 92
| 50, 80
| 8, 61
| –3, 31
| 298–1450
|
|
|
| |
| FeS(a)
|
| кр
|
| –100420
| –100780
| 60, 29
| 50, 54
| 0, 502
| 147, 36
|
| 298–411
|
|
|
| |
| FeS(b)
|
| кр
| a ® b DtH = 4390
|
|
| 50, 42
| 11, 42
|
| 411–1468
|
|
|
| |
| Fe2O3
|
| кр
|
| –822160
| –740340
| 87, 45
| 113, 79
| 97, 74
| 72, 13
| –12, 89
| 298–1000
|
|
|
| | Fe3O4
|
| кр
|
| –111713
| –1104170
| 146, 19
| 151, 79
| 86, 27
| 208, 92
|
| 298–866
|
|
|
| | HBr
|
| г
|
| –56388
|
| 158, 58
| 29, 14
| 26, 15
| 5, 86
| 1, 09
| 298–1600
| 363, 2
| 84, 0
|
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| Продолжение таблицы
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| HCN
|
| г
|
|
|
| 201, 71
| 35, 90
| 39, 37
| 11, 30
| –6, 02
| 298–2500
| 456, 7
| 48, 9
|
|
| HCl
|
| г
|
| –92310
| –95300
| 186, 79
| 29, 14
| 26, 53
| 4, 60
| 1, 09
| 298–2000
| 324, 5
| 81, 5
| 0, 266
|
| HD
|
| г
|
|
| –1470
| 143, 70
| 29, 20
| 29, 25
| –1, 15
| 2, 50
| 298–1500
|
|
|
|
| HNO3
|
| ж
|
| –173000
| –79900
| 156, 16
| 109, 87
| 109, 87
|
|
|
|
|
|
|
| HNO3
|
| г
|
| –133910
| –73780
| 266, 78
| 54, 12
| 54, 12
|
|
|
|
|
|
|
| H2O
|
| кр
|
| –291810
|
|
| 4, 41
| 109, 50
| 44, 47× 10-6
|
| 100–273
|
|
|
|
| H2O
|
| ж
|
| –285830
| –237230
| 69, 95
| 75, 30
| 39, 02
| 76, 64
| 11, 96
| 273–380
|
|
|
|
| H2O
|
| г
|
| –241810
| –228610
| 188, 72
| 33, 61
| 30, 00
| 10, 71
| 0, 33
| 298–2500
| 647, 4
| 238, 3
| 0, 23
|
| H2O2
|
| г
|
| –135880
| –105740
| 234, 41
| 42, 39
| 52, 30
| 11, 88
| –11, 88
| 298–1500
|
|
|
|
| H2S
|
| г
|
| –20600
| –33500
| 205, 70
| 33, 44
| 29, 37
| 15, 40
|
| 298–1800
| 373, 6
| 88, 9
|
| H2SO4
|
| ж
|
| –818990
| –690140
| 156, 90
| 138, 91
| 156, 90
| 28, 90
| –23, 46
| 298–553
|
|
|
|
| HgCl2
|
| кр
|
| –228240
| –180900
| 140, 02
| 73, 91
| 69, 99
| 20, 28
| –1, 89
| 298–550
|
|
|
|
| HgO
| красн.
| кр
|
| –90880
| –58660
| 70, 29
| 44, 88
| 56, 04
| 29, 64
|
| 298–800
|
|
|
|
| KCl
|
| кр
|
| –436680
| –408930
| 82, 55
| 51, 49
| 41, 38
| 21, 76
| 3, 22
| 298–1000
|
|
|
|
| KOH
|
| кр
|
| –424720
| –379220
| 79, 28
| 65, 60
| 42, 66
| 76, 96
|
| 298–522
|
|
|
|
| LiCl
|
| кр
|
| –408270
| –384300
| 59, 30
| 48, 39
| 41, 42
| 23, 40
|
| 298–883
|
|
|
|
| LiOH
|
| кр
|
| –484670
| –439000
| 42, 78
| 49, 58
| 50, 17
| 34, 48
| 9, 50
| 298–744
|
|
|
|
| MgCl2
|
| кр
|
| –644800
| –595300
| 89, 54
| 71, 25
| 79, 08
| 5, 94
| –8, 62
| 298–900
|
|
|
|
| MgO
|
| кр
|
| –601490
| –569270
| 27, 07
| 37, 20
| 48, 98
| 3, 14
| –11, 44
| 298–3000
|
|
|
| Mg(OH)2
|
| кр
|
| –924660
| –833750
| 63, 18
| 76, 99
| 46, 99
| 102, 85
|
| 298–541
|
|
|
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